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34856

Sigma-Aldrich

Dichloromethane

suitable for HPLC, ≥99.8%, contains amylene as stabilizer

Synonym(s):

methylene chloride, Methylene chloride

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About This Item

Empirical Formula (Hill Notation):
CH2Cl2
CAS Number:
75-09-2
Molecular Weight:
84.93
Beilstein/REAXYS Number:
1730800
EC Number:
200-838-9
MDL number:
MFCD00000881
UNSPSC Code:
41116105
PubChem Substance ID:
329755065
NACRES:
NA.04

vapor density

2.9 (vs air)

Quality Level

100

vapor pressure

24.45 psi ( 55 °C)
6.83 psi ( 20 °C)

assay

≥99.8%

form

liquid

autoignition temp.

1223 °F

contains

amylene as stabilizer

expl. lim.

22 %

technique(s)

HPLC: suitable

impurities

free chlorine, in accordance
≤0.001% free acid (as HCl)
≤0.001% non-volatile matter
≤0.02% water (Karl Fischer)

color

APHA: ≤10

transmittance

235 nm, ≥20%
240 nm, ≥50%
245 nm, ≥80%
260 nm, ≥98%

refractive index

n20/D 1.424 (lit.)

bp

39.8-40 °C (lit.)

mp

−95 °C (lit.)

density

1.325 g/mL at 25 °C (lit.)

absorption

in accordance

application(s)

food and beverages

SMILES string

ClCCl

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI key

YMWUJEATGCHHMB-UHFFFAOYSA-N

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General description

Dichloromethane has been tested as a solvent medium for dipyridine-chromium(VI) oxide. Solubility was reported to be 12.5g/100ml. Role of the quantity of TiO2 loading on activated carbon support on dichloromethane photodecomposition has been investigated.

Application

Dichloromethane may be used in ultrasonic baths for cleaning and protection of aluminum coating over atactic-PMMA (poly(methyl methacrylate)) for dielectric studies.

Packaging

View returnable container options.

Preparation Note

Product filtered through a 0.2 μm filter

Other Notes

Pure-Pac® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.
Important notice
  • The article number 34856-4X2.5L will be discontinued. Please order the single bottle 34856-2.5L which is physically identical with the same exact specifications.
  • The article number 34855-6X1L will be discontinued. Please order the single bottle 34856-1L which is physically identical with the same exact specifications.

Recommended products

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Legal Information

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system

wgk_germany

WGK 2

flash_point_f

does not flash

flash_point_c

does not flash

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Glassy dynamics and glass transition in thin polymer layers of PMMA deposited on different substrates.
Erber M, et al.
Macromolecules, 43(18), 7729-7733 (2010)
Effect of activated carbon content in TiO2-loaded activated carbon on photodegradation behaviors of dichloromethane.
Torimoto T, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 103(1), 153-157 (1997)
Dipyridine-chromium (VI) oxide oxidation of alcohols in dichloromethane.
Collins JC, et al.
Tetrahedron Letters, 9(30), 3363-3366 (1968)
Amélie Kochem et al.
Inorganic chemistry, 51(20), 10557-10571 (2012-09-28)
Square planar cobalt(II) complexes of salen ligands N,N'-bis(3-tert-butyl-5R-salicylidene)-1,2-cyclohexanediamine), where R = OMe (1) and tert-butyl (2), were prepared. 1 and 2 were electrochemically reversibly oxidized into cations [1-H(2)O](+) and [2-H(2)O](+) in CH(2)Cl(2). The chemically generated [1-H(2)O](SbF(6))·0.68 H(2)O·0.82CH(2)Cl(2) and [2-H(2)O](SbF(6))·0.3H(2)O·0.85CH(2)Cl(2) were
Angharad M Roberts et al.
Science translational medicine, 7(270), 270ra6-270ra6 (2015-01-16)
The recent discovery of heterozygous human mutations that truncate full-length titin (TTN, an abundant structural, sensory, and signaling filament in muscle) as a common cause of end-stage dilated cardiomyopathy (DCM) promises new prospects for improving heart failure management. However, realization
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