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34850

Sigma-Aldrich

Acetone

suitable for HPLC, ≥99.8%

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About This Item

Linear Formula:
CH3COCH3
CAS Number:
67-64-1
Molecular Weight:
58.08
Beilstein/REAXYS Number:
635680
EC Number:
200-662-2
MDL number:
MFCD00008765
UNSPSC Code:
41116105
eCl@ss:
39021201
PubChem Substance ID:
329755060

vapor density

2 (vs air)

Quality Level

100

vapor pressure

184 mmHg ( 20 °C)

assay

≥99.8%

form

liquid

expl. lim.

13.2 %

technique(s)

HPLC: suitable

impurities

≤0.0005% non-volatile matter
≤0.002% free acid (as CH3COOH)
≤0.1% water (Karl Fischer)

transmittance

330 nm, ≥15%
335 nm, ≥50%
340 nm, ≥80%
350 nm, ≥98%

refractive index

n20/D 1.359 (lit.)

pH

5-6 (20 °C, 395 g/L)

bp

56 °C/760 mmHg (lit.)

mp

−94 °C (lit.)

density

0.791 g/mL at 25 °C (lit.)

format

neat

SMILES string

CC(C)=O

InChI

1S/C3H6O/c1-3(2)4/h1-2H3

InChI key

CSCPPACGZOOCGX-UHFFFAOYSA-N

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General description

Mixtures of TiO2 (P25) with rare earth oxides (La2O3 or Y2O3) calcined at 700°C or 650°C efficiently causes oxidation of acetone. Its Aldol condensation in vapor-phase has been investigated over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions. It undergoes Aldol condensation in the presence of Mg-Al layered double hydroxides (LDH) as catalysts and Cl- and/or CO32- as compensating anions to afford diacetone alcohol and mesityl oxide. Enantioselective Aldol condensation of acetone with various isatins in the presence of dipeptides (catalyst) has been described.

Application

Acetone has been used in the preparation of 13wt% amorphous poly (lactic acid) (PLA) solution, which was required for the preparation of electrospun PLA membranes.
Acetone′s luminesence intensity is dependent upon the solution components . The absorption of UV light by acetone, results in its photolysis and the production of radials .

Packaging

View returnable container options.

Other Notes

Important notice
  • The article number 34850-4X2.5L will be discontinued. Please order the single bottle 34850-2.5L which is physically identical with the same exact specifications.
  • The article number 34850-6X1L will be discontinued. Please order the single bottle 34850-1L which is physically identical with the same exact specifications.

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pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH066

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

1.4 °F - closed cup

flash_point_c

-17.0 °C - closed cup

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Acetone

Development of eco-efficient micro-porous membranes via electrospinning and annealing of poly (lactic acid).
Li L, et al.
Journal of Membrane Science, 436, 57-67 (2013)
Gianluigi Luppi et al.
The Journal of organic chemistry, 70(18), 7418-7421 (2005-08-27)
[reaction: see text] The aldol condensation of acetone with several isatins is described. The desired compound was obtained in quantitative yield and with good enantioselectivities up to 77%. The best results were obtained with 10 mol % H-D-Pro-L-beta3-hPhg-OBn as a
Base catalysis for the synthesis of α,β-unsaturated ketones from the vapor-phase aldol condensation of acetone.
Di Cosimo JI, et al.
Applied Catalysis A: General, 137(1), 149-166 (1996)
Aldol condensation of acetone over layered double hydroxides of the meixnerite type.
Tichit D, et al.
Applied Clay Science, 13(5), 401-415 (1998)
An investigation on photocatalytic activities of mixed TiO2-rare earth oxides for the oxidation of acetone in air.
Lin J and Jimmy CY.
Journal of Photochemistry and Photobiology A: Chemistry, 116(1), 63-67 (1998)
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