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Sigma-Aldrich

Iron(III) chloride

greener alternative

reagent grade, 97%

Synonym(s):

Ferric chloride, Iron trichloride, Molysite

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About This Item

Linear Formula:
FeCl3
CAS Number:
Molecular Weight:
162.20
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

reagent grade

Quality Level

vapor density

5.61 (vs air)

vapor pressure

1 mmHg ( 194 °C)

assay

97%

form

powder

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

304 °C (lit.)

greener alternative category

SMILES string

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

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General description

Iron(III) chloride is a mild oxidizing agent and participates in various carbon-carbon-bond forming reactions. On crystallization with water, it forms hydrates. It can be prepared by reacting chlorine with the scrap iron at approximately 650°C.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Iron(III) chloride (Ferric Chloride, FeCl3) has been used as a surface modulator for the characterization of wines by fingerprinting technology. It has been used for the quantitative estimation of sulfide in various biological samples.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resitance properties.

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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"Iron (III) chloride-catalyzed convenient one-pot synthesis of homoallyl benzyl ethers starting from aldehydes"
Watahiki T, et al.
Organic Letters, 5(17), 3045-3048 (2003)
Novel non-specific liquid fingerprint technology for wine analysis: a feasibility study.
Siivonen JJ, et al.
Australian Journal of Grape and Wine Research, 20(2), 172-177 (2014)
"Iron (III) chloride-based mild synthesis of phenanthrene and its application to total synthesis of phenanthroindolizidine alkaloids"
Wang L-K, et al.
Tetrahedron, 64(32), 7504-7510 (2008)
Yuanyuan Kong et al.
Cell death & disease, 10(9), 624-624 (2019-08-20)
Recent findings demonstrate that aberrant downregulation of the iron-exporter protein, ferroportin (FPN1), is associated with poor prognosis and osteoclast differentiation in multiple myeloma (MM). Here, we show that FPN1 was downregulated in MM and that clustered regularly interspaced short palindromic
Mirjam Visscher et al.
Journal of the American Society for Mass Spectrometry, 30(9), 1790-1800 (2019-06-30)
Atherosclerosis is a lipid and inflammation-driven disease of the arteries that is characterized by gradual buildup of plaques in the vascular wall. A so-called vulnerable plaque, consisting of a lipid-rich necrotic core contained by a thin fibrous cap, may rupture

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