D93503
Silver diethyldithiocarbamate
ACS reagent, 99%
Synonym(s):
DETC, Diethyldithiocarbamic acid silver salt
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About This Item
Linear Formula:
(C2H5)2NCSSAg
CAS Number:
Molecular Weight:
256.14
Beilstein/REAXYS Number:
3718150
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Recommended Products
grade
ACS reagent
Quality Level
assay
99%
form
powder
reaction suitability
core: silver
reagent type: catalyst
mp
172-175 °C (lit.)
storage temp.
2-8°C
SMILES string
CCN(CC)C(=S)S[Ag]
InChI
1S/C5H11NS2.Ag/c1-3-6(4-2)5(7)8;/h3-4H2,1-2H3,(H,7,8);/q;+1/p-1
InChI key
NSVHDIYWJVLAGH-UHFFFAOYSA-M
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Related Categories
General description
Silver diethyldithiocarbamate is used to introduce diethyldithiocarbamato ligand and for the determination of arsenic.
Application
Reagent for the detection of arsenic and for the introduction of the diethyldithiocarbamato ligand.
Silver diethyldithiocarbamate (AgDDC) may be used in the preparation of adducts of triorganophosphines and diphosphines.
Also used for colorimetric determination of small quantities of arsenic
Spin trap used in conjunction with Fe2+ to detect NO in brain, kidney, liver, and other tissues. Simultaneous direct measurement of NO* and pO2 has been reported. A copper chelator, it has been used to quantitate copper in biological materials by ESR and is an inhibitor of superoxide dismutase, ascorbate oxidase, and other enzymes.
Biochem/physiol Actions
Inhibits induction of macrophage nitric oxide synthase.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis and structural characterization of adducts of silver (I) diethyldithiocarbamate with P-donor ligands.
Di Nicola C, et al.
Inorgorganica Chimica Acta, 360(9), 2935-2943 (2007)
Analytical Chemistry, 31, 1589-1589 (1959)
Inorganic Chemistry, 32, 3565-3565 (1993)
Chem. Abstr., 117, 219549d-219549d (1992)
Hunjing Baohu, 23-23 (1991)
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