Skip to Content
MilliporeSigma
All Photos(4)

Documents

1.01843

Supelco

tert-Butyl methyl ether

EMPLURA®

Synonym(s):

tert-Butyl methyl ether, Methyl tert-butyl ether, MTB, MTBE

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(CH3)3COCH3
CAS Number:
Molecular Weight:
88.15
MDL number:
UNSPSC Code:
12191502
EC Index Number:
216-653-1
NACRES:
NA.05

vapor pressure

268 hPa ( 20 °C)

Quality Level

product line

EMPLURA®

assay

≥99% (GC)

form

liquid

autoignition temp.

460 °C

potency

>2000 mg/kg LD50, oral (Rat)
>2000 mg/kg LD50, skin (Rabbit)

expl. lim.

1.5-8.5 % (v/v)

impurities

≤0.001% Free acid (as CH3COOH)
≤0.005% Peroxide (as H2O2)
≤0.05% Water

evapn. residue

≤0.005%

kinematic viscosity

0.464 cSt(20 °C)

bp

55.3 °C/1013 hPa

mp

-108.6 °C

transition temp

flash point -28 °C

solubility

42 g/L

density

0.74 g/cm3 at 20 °C

storage temp.

2-30°C

InChI

1S/C5H12O/c1-5(2,3)6-4/h1-4H3

InChI key

BZLVMXJERCGZMT-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

EMPLURA® is our low-cost alternative to high-purity qualities. With EMPLURA we offer a range of solvents for a plurality of basic applications in non-regulated industries and for less demanding applications, preparative laboratory work and cleaning purposes. EMPLURA solvents provide adequate specifications with the most important parameters.

Application


  • Evidence for HOOO radicals in the formation of alkyl hydrotrioxides (ROOOH) and hydrogen trioxide (HOOOH) in the ozonation of C-H bonds in hydrocarbons.: This research used tert-Butyl methyl ether to investigate the formation of hydrotrioxides and hydrogen trioxide in the ozonation of hydrocarbons, providing insights into radical chemistry and ozonation processes (Cerkovnik et al., 2002).

  • Determination of ochratoxin A in baby food by immunoaffinity column cleanup with liquid chromatography: interlaboratory study.: The study employed tert-Butyl methyl ether in the cleanup process for detecting ochratoxin A in baby food, demonstrating its effectiveness in ensuring food safety through reliable analytical methods (Burdaspal et al., 2001).

  • Sensitive high-performance liquid chromatography/mass spectrometry method for determination of steviol in rat plasma.: This paper highlights the use of tert-Butyl methyl ether in developing a sensitive HPLC/MS method for analyzing steviol in biological samples, showcasing its application in pharmacokinetic and toxicological studies (Wang et al., 2004).

  • Comparative fatty acid selectivity of lipases in esterification reactions with glycerol and diol analogues in organic media.: The research employed tert-Butyl methyl ether to investigate lipase selectivity in esterification reactions, illustrating its importance in biocatalysis and industrial applications of enzymatic processes (Lee & Parkin, 2000).

  • Analysis of coumarin 7-hydroxylation activity of cytochrome P450 2A6 using random mutagenesis.: This study utilized tert-Butyl methyl ether to analyze enzyme activity in cytochrome P450, demonstrating its utility in biochemical assays and the study of enzyme kinetics (Kim et al., 2005).

Analysis Note

Purity (GC): ≥ 99.0 %
Identity (IR): conforms
Free acid (as CH₃COOH): ≤ 0.001 %
Density (d 20 °C/ 4 °C): 0.740 - 0.742
Peroxide (as H₂O₂): ≤ 0.005 %
Evaporation residue: ≤ 0.005 %
Water: ≤ 0.05 %

Legal Information

EMPLURA is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2

wgk_germany

WGK 1


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 7

1 of 7

tert-Butyl methyl ether analytical standard

Supelco

08603

tert-Butyl methyl ether

tert-Butyl methyl ether HPLC grade, suitable for HPLC, 99.8%

Supelco

293210

tert-Butyl methyl ether

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service