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765910

Sigma-Aldrich

Potassium tri(3,5-dimethyl-1-pyrazolyl)borohydride

97%

Synonym(s):

Potassium hydrotris(3,5-dimethylpyrazol-1-yl)borate, Scorpionates, Tp ligand

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About This Item

Empirical Formula (Hill Notation):
C15H22BKN6
CAS Number:
17567-17-8
Molecular Weight:
336.28
MDL number:
MFCD00040342
UNSPSC Code:
12352300
PubChem Substance ID:
329767194
NACRES:
NA.22

Quality Level

100

assay

97%

form

solid

mp

292-301 °C

SMILES string

[K+].Cc1cc(C)n(n1)[BH-](n2nc(C)cc2C)n3nc(C)cc3C

InChI

1S/C15H22BN6.K/c1-10-7-13(4)20(17-10)16(21-14(5)8-11(2)18-21)22-15(6)9-12(3)19-22;/h7-9,16H,1-6H3;/q-1;+1

InChI key

NTWZGFNSHCFHIJ-UHFFFAOYSA-N

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Related Categories

Application

Scorpionate ligand

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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Brendan J Liddle et al.
The Journal of organic chemistry, 72(25), 9794-9797 (2007-11-13)
The preparation of three tris(pyrazolyl)toluidines from trifluoromethylaniline reagents is described that likely takes advantage of (quinoidal) resonance-stabilized activation of the C-F bonds. Subsequent transformations lead to two additional (for a total of five new) tris(pyrazolyl)methylaryls. This simple reaction is remarkable

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