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Sigma-Aldrich

Hexylamine

99%

Synonym(s):

1-Aminohexane

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About This Item

Linear Formula:
CH3(CH2)5NH2
CAS Number:
111-26-2
Molecular Weight:
101.19
Beilstein/REAXYS Number:
1731298
EC Number:
203-851-8
MDL number:
MFCD00008240
UNSPSC Code:
12352100
PubChem Substance ID:
24853140
NACRES:
NA.22

Quality Level

200

assay

99%

form

liquid

expl. lim.

2.1-9.3 %

refractive index

n20/D 1.418 (lit.)

bp

131-132 °C (lit.)

mp

−23 °C (lit.)

density

0.766 g/mL at 25 °C (lit.)

SMILES string

CCCCCCN

InChI

1S/C6H15N/c1-2-3-4-5-6-7/h2-7H2,1H3

InChI key

BMVXCPBXGZKUPN-UHFFFAOYSA-N

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Application

Hexylamine can be used:
  • As an initiator to synthesize defined polypeptides by primary amine-initiated N-carboxyanhydride ring opening polymerization reaction.
  • As a reactant to modify alkanethiol monolayers at polycrystalline gold surfaces via amide bond formation reaction.
  • To functionalize the surface of MWCNT, graphene oxide, and polyurethanes. These functionalized composites materials find applications in absorption, CO2 capture, and as barrier materials.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

80.6 °F - closed cup

flash_point_c

27 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

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N-Hexylmethylamine

Adsorption behaviour of n-hexylamine at the Hg/water interphase and its comparison with a molecular model accounting for local order.
Carla M, et al.
J. Electroanal. Chem. Interfac. Electrochem., 197(1), 123-141 (1986)
Jiong Zou et al.
Macromolecules, 46(10), 4223-4226 (2013-06-25)
A facile N
Julien Roeser et al.
Rapid communications in mass spectrometry : RCM, 27(4), 546-552 (2013-01-17)
Cleavage of peptide bonds C-terminal to tyrosine and tryptophan after electrochemical oxidation may become a complementary approach to chemical and enzymatic cleavage. A chemical labeling approach specifically targeting reactive cleavage products is presented here and constitutes a promising first step
Leon Coulier et al.
Analytical chemistry, 78(18), 6573-6582 (2006-09-15)
We have developed an analytical method, consisting of ion-pair liquid chromatography coupled to electrospray ionization mass spectrometry (IP-LC-ESI-MS), for the simultaneous quantitative analysis of several key classes of polar metabolites, like nucleotides, coenzyme A esters, sugar nucleotides, and sugar bisphosphates.
J P Wolfe et al.
The Journal of organic chemistry, 65(4), 1144-1157 (2000-05-18)
Mixtures of Pd(2)(dba)(3) or Pd(OAc)(2) and BINAP catalyze the cross-coupling of amines with a variety of aryl bromides. Primary amines are arylated in high yield, and certain classes of secondary amines are also effectively transformed. The process tolerates the presence
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Protocols

Catalytic Amide Bond Formation Protocol

Information on the Amide bond and the Catalytic Amide Bond Formation Protocol. Amidation of amines and alcohols. The amide bond, an important linkage in organic chemistry, is a key functional group in peptides, polymers, and many natural products and pharmaceuticals.

GC Analysis of Primary Amines on Carbowax® Amine

Separation of Propylamine; Butylamine; Pentylamine; Hexylamine; Heptylamine; Octylamine; Nonylamine; Decylamine

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