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160989

Sigma-Aldrich

3-Ethoxysalicylaldehyde

97%

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About This Item

Linear Formula:
C2H5OC6H3-2-(OH)CHO
CAS Number:
Molecular Weight:
166.17
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

form

solid

bp

263-264 °C (lit.)

mp

66-68 °C (lit.)

SMILES string

CCOc1cccc(C=O)c1O

InChI

1S/C9H10O3/c1-2-12-8-5-3-4-7(6-10)9(8)11/h3-6,11H,2H2,1H3

InChI key

OFQBYHLLIJGMNP-UHFFFAOYSA-N

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Application

3-Ethoxysalicylaldehyde was used in the preparation of:
  • Schiff base ligand via condensation with trans-1,2-diaminocyclohexane
  • substituted salen-type Schiff base ligands
  • a new Schiff base, 2-ethoxy-6-[(3-methylaminopropylimino)methyl]phenol, via reaction with N-methylpropane-1,3-diamine

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Syntheses, characterization, and magnetic properties of a series of diphenoxo-bridged discrete dinuclear M(II)Ln(III) complexes (M = Cu or Ni, Ln = Ce-Yb) derived from the compartmental Schiff base ligand, H(2)L, obtained on condensation of 3-ethoxysalicylaldehyde with trans-1,2-diaminocyclohexane, are described. Single
Hydroxylation of phenol catalyzed by oxovanadium (IV) of salen-type schiff base complexes with hydrogen peroxide.
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Catalysis Letters, 136(3-4), 228-233 (2010)
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Salophen (N,N'-bis-(salicylidene)-o-phenylenediamine) is a Schiff base, which is weakly emissive in solution, but strongly emissive in the solid state. The trend is reversed in its aluminium complex (SalAl

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