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104426

Sigma-Aldrich

Tetrafluoroterephthalonitrile

99%

Synonym(s):

2,3,5,6-Tetrafluoro-1,4-dicyanobenzene

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About This Item

Linear Formula:
C6F4-1,4-(CN)2
CAS Number:
1835-49-0
Molecular Weight:
200.09
EC Number:
217-397-3
MDL number:
MFCD00001776
UNSPSC Code:
12352100
PubChem Substance ID:
24846643
NACRES:
NA.22

Quality Level

100

assay

99%

form

solid

mp

197-199 °C (lit.)

solubility

acetone: soluble

SMILES string

Fc1c(F)c(C#N)c(F)c(F)c1C#N

InChI

1S/C8F4N2/c9-5-3(1-13)6(10)8(12)4(2-14)7(5)11

InChI key

PCRSJGWFEMHHEW-UHFFFAOYSA-N

Related Categories

General description

Tetrafluoroterephthalonitrile reacts with alkyl Grignard reagents to form corresponding 4-alkyltetrafluorobenzonitriles. Tetrafluoroterephthalonitrile acts as a four-electron donor ligand and forms tungsten(II)η2-nitrile complexes.

Application

Tetrafluoroterephthalonitrile can be used in the synthesis of Polymers of Intrinsic Microporosity (PIM). Tetrafluoroterephthalonitrile was used to study ultraviolet (UV)-rearranged polymers of PIM-1 membranes for efficient separation of H2 and CO2 .

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Rhys Short et al.
Chemical communications (Cambridge, England), 47(24), 6822-6824 (2011-05-19)
Microporous polymers derived from the 1,2- and 1,4-regioisomers of di(3',4'-dihydroxyphenyl)tetraphenylbenzene have very different properties with the former being composed predominantly of cyclic oligomers whereas the latter is of high molar mass suitable for the formation of robust solvent-cast films of
The mono-alkyldecyanation of tetrafluoroterephthalonitrile by reaction with Grignard reagents.
Milner DJ.
Journal of Organometallic Chemistry, 302(2), 147-152 (1986)
Mohammed N Alnajrani et al.
Scientific reports, 10(1), 794-794 (2020-01-23)
Traces of antibiotics within domestic and industrial effluents have toxic impact on human health as well as surrounding flora and fauna. Potential increase in antibiotic resistance of microorganisms is likely to rise due to the incomplete removal of antibiotics by
Donya Ramimoghadam et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 20(12), 1613-1623 (2019-05-09)
There has been recent interest in polymers of intrinsic microporosity (PIMs) for solid-state hydrogen-storage materials; however, the gas-sorption properties and conditions for hydrogen uptake are relatively unexplored. PIM-1 has been synthesised using the condensation reaction between 3,3,3,3-tetramethyl-1,1-spirobisindane-5,5,6,6-tetraol and 2,3,5,6-tetrafluorophthalonitrile as
Allergic contact dermatitis from tetrafluoroterephthalonitrile and TFX diamine.
A J Carmichael et al.
Contact dermatitis, 20(3), 233-234 (1989-03-01)
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