CRM67344
Indoxacarb
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonym(s):
Methyl 7-chloro-2,5-dihydro-2-[N-(methoxycarbonyl)-4-(trifluoromethoxy)anilinocarbonyl]indeno[1,2-e][1,3,4]oxadiazine-4a(3H)carboxylate
About This Item
Recommended Products
grade
certified reference material
TraceCERT®
Quality Level
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
format
neat
SMILES string
COC(=O)N(C(=O)N1CO[C@]2(Cc3cc(Cl)ccc3C2=N1)C(=O)OC)c4ccc(OC(F)(F)F)cc4
InChI
1S/C22H17ClF3N3O7/c1-33-18(30)21-10-12-9-13(23)3-8-16(12)17(21)27-28(11-35-21)19(31)29(20(32)34-2)14-4-6-15(7-5-14)36-22(24,25)26/h3-9H,10-11H2,1-2H3/t21-/m0/s1
InChI key
VBCVPMMZEGZULK-NRFANRHFSA-N
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General description
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Indoxacarb is a non-systemic and chiral oxadiazine insecticide. It is a sodium channel antagonist and blocks the voltage-dependent sodium channels in the neurons thereby impairing nervous function and feeding, causing paralysis and death of the insect. Absorbed by ingestion and contact, it is used against sucking insects, mainly lepidopterans pests on a wide variety of crops.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, indoxacarb is approved for use as a plant protection agent in the European Union. The Commission Regulation (EU) 2015/845 of 27th May 2015 sets a maximum residue limit (MRL) of 0.02 mg/kg in fresh/frozen fruits and tree nuts for indoxacarb (measured as a sum of indoxacarb and its R enantiomer). Indoxacarb has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Application
The indoxacarb CRM may also find the following uses:
- Investigate the persistence, distribution, and risk assessment of indoxacarb residues in tomato and soil samples by using gas chromatography with electron ionization mass spectrometry
- Simultaneous enantioselective analysis of cis-epoxiconazole and indoxacarb residues in different tea, black tea infusion, and soil samples by chiral HPLC coupled with tandem quadrupole time-of-flight mass spectrometry (Q-TOF/MS)
- To develop and validate a method for the determination of pesticide residues of iprovalicarb, indoxacarb, and boscalid in grape and wine samples by gas chromatography/ion trap mass spectrometry (GC/ITMS)
- Assess chili fruit samples collected at different time intervals for the presence of indoxacarb and thiamethoxam by gas-liquid chromatography-electron capture detection (GLC-ECD) and gas chromatography-mass spectrometry (GC-MS/MS)
Legal Information
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1B - STOT RE 1
Storage Class Code
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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