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912778

Sigma-Aldrich

sBOX(iPr)

≥95%

Synonym(s):

Diisopropyl 2,2′-(cyclopropane-1,1-diyl)(4S,4′S)-bis(4,5-dihydrooxazole-4-carboxylate)

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About This Item

Empirical Formula (Hill Notation):
C17H24N2O6
CAS Number:
2328083-86-7
Molecular Weight:
352.38
UNSPSC Code:
12352200

Assay

≥95%

form

(Powder or Solid or Chunks)

storage temp.

2-8°C

Inchi Code

1S/C17H24N2O6/c1-9(2)24-13(20)11-7-22-15(18-11)17(5-6-17)16-19-12(8-23-16)14(21)25-10(3)4/h9-12H,5-8H2,1-4H3/t11-,12-/m0/s1

InChI key

JNHLVSXLRZSBTG-RYUDHWBXSA-N

Related Categories

Application

sBOX(iPr) is a serine-derived chiral bisoxazoline ligand. The additional coordinating functionality provided by the esters enables new reactivity compared to traditional BOX ligands. sBOX(iPr) has been shown to be an optimal ligand for the electrocatalytic cyanophosphorylation as well as hydrocyanation of vinylarenes.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

Other Notes

New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Niankai Fu et al.
Journal of the American Chemical Society, 141(37), 14480-14485 (2019-09-10)
In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective catalytic methods powered by electricity remain rare. In this work, we report the development of a highly enantioselective method for the electrochemical cyanophosphinoylation of vinylarenes. A new

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