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908703

Sigma-Aldrich

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

≥95%

Synonym(s):

[(4,4′-di-tert-butyl-2,2′-bipyridine)-bis-(5-methyl-2-(5-fluoro-phenyl)-pyridine)-iridium(III)] hexafluorophosphate

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About This Item

Empirical Formula (Hill Notation):
C42H42F8IrN4P
CAS Number:
808142-88-3
Molecular Weight:
977.99
UNSPSC Code:
12352101

Assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

photocatalyst activation

450 nm

Related Categories

Application

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Direct, enantioselective α-alkylation of aldehydes using simple olefins

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds

Decarboxylative sp3 C-N coupling via dual copper and photoredox catalysis

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Ir(p-F-ppy)3

Sigma-Aldrich

900538

Ir(p-F-ppy)3

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6 ≥95%

902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%

Sigma-Aldrich

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6

Ir(p-CF3-ppy)3 ≥95%

Sigma-Aldrich

904694

Ir(p-CF3-ppy)3

Ir[dF(t-Bu)-ppy]3

Sigma-Aldrich

900570

Ir[dF(t-Bu)-ppy]3

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6 ≥95%

Sigma-Aldrich

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6

Ir[p-F(t-Bu)-ppy]3

Sigma-Aldrich

900539

Ir[p-F(t-Bu)-ppy]3

Copper(I) thiophene-2-carboxylate

Sigma-Aldrich

682500

Copper(I) thiophene-2-carboxylate

Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)

Sigma-Aldrich

658383

Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)

Ru(p-CF3-bpy)3 (BF4)2 ≥95%

Sigma-Aldrich

903426

Ru(p-CF3-bpy)3 (BF4)2

Yufan Liang et al.
Nature, 559(7712), 83-88 (2018-06-22)
Over the past three decades, considerable progress has been made in the development of methods to construct sp2 carbon-nitrogen (C-N) bonds using palladium, copper or nickel catalysis1,2. However, the incorporation of alkyl substrates to form sp3 C-N bonds remains one
Yong Yao Loh et al.
Science (New York, N.Y.), 358(6367), 1182-1187 (2017-11-11)
Deuterium- and tritium-labeled pharmaceutical compounds are pivotal diagnostic tools in drug discovery research, providing vital information about the biological fate of drugs and drug metabolites. Herein we demonstrate that a photoredox-mediated hydrogen atom transfer protocol can efficiently and selectively install
Andrew G Capacci et al.
Nature chemistry, 9(11), 1073-1077 (2017-10-25)
Although the α-alkylation of ketones has already been established, the analogous reaction using aldehyde substrates has proven surprisingly elusive. Despite the structural similarities between the two classes of compounds, the sensitivity and unique reactivity of the aldehyde functionality has typically

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