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86730

Sigma-Aldrich

2,3,4,6-Tetra-O-benzyl-D-glucopyranose

≥98.0% (TLC)

Synonym(s):

2,3,4,6-Tetra-O-benzyl-glucopyranose, 2,3,4,6-Tetrakis-O-(phenylmethyl)-D-glucopyranose

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About This Item

Empirical Formula (Hill Notation):
C34H36O6
CAS Number:
4132-28-9
Molecular Weight:
540.65
MDL number:
MFCD00066004
UNSPSC Code:
12352201
PubChem Substance ID:
57653190
NACRES:
NA.22

Quality Level

100

Assay

≥98.0% (TLC)

form

solid

optical activity

[α]20/D +49±2°, c = 2% in dioxane

mp

151-156 °C

shipped in

wet ice

storage temp.

−20°C

SMILES string

OC1O[C@H](COCc2ccccc2)[C@@H](OCc3ccccc3)[C@H](OCc4ccccc4)[C@H]1OCc5ccccc5

InChI

1S/C34H36O6/c35-34-33(39-24-29-19-11-4-12-20-29)32(38-23-28-17-9-3-10-18-28)31(37-22-27-15-7-2-8-16-27)30(40-34)25-36-21-26-13-5-1-6-14-26/h1-20,30-35H,21-25H2/t30-,31-,32+,33-,34?/m1/s1

InChI key

OGOMAWHSXRDAKZ-BKJHVTENSA-N

Other Notes

Important D-glucopyranose derivative for glucosylations and other reactions ; Preparation of the α-glucopyranosyl chloride ; Synthesis of 1-C-α-D-glucopyranose derivatives

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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P. Allevi et al.
Journal of the Chemical Society. Chemical Communications, 1245-1245 (1987)
A.A. Pavia et al.
Carbohydrate Research, 79, 79-79 (1980)
P. Allevi et al.
Journal of the Chemical Society. Chemical Communications, 101-101 (1987)
S. Koto et al.
Bulletin of the Chemical Society of Japan, 53, 1761-1761 (1980)

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