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774448

Sigma-Aldrich

4-Chlorophenylmagnesium bromide solution

greener alternative

1.0 M in 2-methyltetrahydrofuran

Synonym(s):

(4-Chlorophenyl)magnesium bromide, p-Chlorophenylmagnesium bromide

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About This Item

Linear Formula:
ClC6H4MgBr
CAS Number:
873-77-8
Molecular Weight:
215.76
MDL number:
MFCD00009926
UNSPSC Code:
12352103
PubChem Substance ID:
329767685
NACRES:
NA.22

form

solution

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

greener alternative product characteristics

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

concentration

1.0 M in 2-methyltetrahydrofuran

density

1.005 g/mL at 25 °C

greener alternative category

Aligned,

storage temp.

2-8°C

SMILES string

Clc1ccc([Mg]Br)cc1

InChI

1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1

InChI key

CDEMHJCJMMOFMB-UHFFFAOYSA-M

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Find details here.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Hazard Statements

H225 - H302 - H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Supplementary Hazards

EUH014 - EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

8.6 °F - closed cup

Flash Point(C)

-13.0 °C - closed cup

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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