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771147

Sigma-Aldrich

1-Trifluoromethyl-1,2-benziodoxol-3-(1H)-one

60 wt. %, contains 40 wt. % Celatom® FW-80 as additive

Synonym(s):

Togni Reagent II

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About This Item

MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

form

solid

Quality Level

contains

40 wt. % Celatom® FW-80 as additive

reaction suitability

reaction type: C-C Bond Formation

concentration

60 wt. %

mp

150-158 °C

storage temp.

2-8°C

SMILES string

FC(F)(F)[I]1OC(=O)c2ccccc12

InChI

1S/C8H4F3IO2/c9-8(10,11)12-6-4-2-1-3-5(6)7(13)14-12/h1-4H

InChI key

XHEOXSQMBWJOKP-UHFFFAOYSA-N

Application

Electrophilic trifluoromethylating reagent has shown to be one of the more robust trifluoromethylation reagents on the market. However, a recent report has showed this product to have potential dangerous self-reactivity neat. We now offer a less self-reactive material mixed down in Celatom®, a silica-based adsorbent, which significantly reduces self-reactivity allowing for safer shipping and storage.

Legal Information

Celatom is a registered trademark of EP Minerals, LLC

related product

Product No.
Description
Pricing

Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3

Target Organs

Lungs, Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Fiederling, N.;
Organic Process Research & Development, 17, 318-319 (2013)

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