714836
Iodine monochloride solution
1 M in acetic acid
Synonym(s):
Chloroiodide solution, Wijs solution
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About This Item
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form
solution
Quality Level
concentration
1 M in acetic acid
density
1.143 g/mL at 25 °C
SMILES string
ClI
InChI
1S/ClI/c1-2
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
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General description
Iodine monochloride is an inorganic reagent used in the iodination and chloroiodination of aromatic and unsaturated compounds, respectively. It is also used to cleave carbon-metal bonds.
Application
Iodine monochloride can be used:
- As a reagent in the preparation of α-iodo β-ketosulfones from β-ketosulfones.
- In the synthesis of 3-(4-bromo-2-methylphenyl)-4-iodosydnone, which is further used to prepare substituted pyrazoles.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
105.1 °F
Flash Point(C)
40.6 °C
Certificates of Analysis (COA)
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Synthesis of α-iodo β-ketosulfones and α-iodo methylsulfones using iodine monochloride
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Journal of chromatography, 423, 41-50 (1987-12-25)
Low-level adsorption on the stationary phase has been studied using immunochemical reagents. An immunoaffinity column has been evaluated using affinity-purified radioisotope-labeled monoclonal antibodies. Recovery experiments including continuous immunosorbent monitoring have been performed. Proper characterization of an immunoaffinity separation can result
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Rat muscle glyceraldehyde-3-phosphate dehydrogenase was reacted with two reagents aimed at the highly reactive cysteine-149 residue in the active site of the enzyme. The enzyme was rapidly inactivated by iodine monochloride. Complete inactivation occurred when approx. 6 mol ICl were
Journal of hazardous materials, 183(1-3), 132-137 (2010-08-03)
The removal of Hg(0) by the homogenous gas-phase reaction and particle-induced reaction was investigated under various conditions. Iodine monochloride was found to be efficient for Hg(0) oxidation, with the apparent 2nd-order rate constant of about 10.5(±0.3)×10(-17) cm(3) molecules(-1) s(-1) and
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There are conflicting ideas regarding the location of the carboxyl-terminal regions of cross-linked gamma-chain dimers in double-stranded fibrin fibrils. Some investigators believe that the chains are always oriented longitudinally along each fibril strand and traverse the contacting ends of abutting
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