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359327

Sigma-Aldrich

N-Hexylmethylamine

96%

Synonym(s):

N-Methylhexylamine

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About This Item

Linear Formula:
CH3NH(CH2)5CH3
CAS Number:
35161-70-7
Molecular Weight:
115.22
Beilstein:
1731685
EC Number:
252-410-6
MDL number:
MFCD00042908
UNSPSC Code:
12352100
PubChem Substance ID:
24862068
NACRES:
NA.22

Quality Level

200

Assay

96%

form

liquid

refractive index

n20/D 1.416 (lit.)

bp

140-142 °C (lit.)

density

0.76 g/mL at 25 °C (lit.)

SMILES string

CCCCCCNC

InChI

1S/C7H17N/c1-3-4-5-6-7-8-2/h8H,3-7H2,1-2H3

InChI key

XJINZNWPEQMMBV-UHFFFAOYSA-N

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General description

N-Hexylmethylamine is an acyclic secondary amine. Ruthenium-catalyzed reaction of N-hexylmethylamine with styrene has been reported. Transition metal-catalyzed intermolecular hydroamination of N-hexylmethylamine with 2-vinylnaphthalene has been reported.

Application

N-Hexylmethylamine may be used in the synthesis of dialkyldithiocarbamato cadmium complexes Cd[S2CNRR′]2.

Signal Word

Danger

Hazard Statements

H226 - H302 - H314

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

87.8 °F - closed cup

Flash Point(C)

31 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Masaru Utsunomiya et al.
Journal of the American Chemical Society, 126(9), 2702-2703 (2004-03-05)
A ruthenium-catalyzed intermolecular, anti-Markovnikov hydroamination of vinylarenes with secondary aliphatic and benzylic amines is reported. The combination of Ru(cod)(2-methylallyl)2, 1,5-bis(diphenylphosphino)pentane, and triflic acid was the most effective catalyst of those tested. Control reactions conducted without ligand or acid did not
The synthesis of SiO2@ CdS nanocomposites using single-molecule precursors.
Monteiro OC, et al.
Chemistry of Materials, 14(7), 2900-2904 (2002)
Masaru Utsunomiya et al.
Journal of the American Chemical Society, 125(47), 14286-14287 (2003-11-20)
A transition metal-catalyzed intermolecular hydroamination of vinylarenes with alkylamines is reported. The combination of Pd(O2CCF3)4, DPPF, and TfOH was the most effective catalyst of those tested. Control experiments without palladium, acid, or ligand all occurred in low yield. The reaction

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