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248401

Sigma-Aldrich

Magnesium methyl carbonate solution

2.0 M in DMF

Synonym(s):

MMC, Methoxymagnesium methyl carbonate, Methyl methoxymagnesium carbonate, Stile’s reagent

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About This Item

Linear Formula:
CH3OMgOCO2CH3
CAS Number:
4861-79-4
Molecular Weight:
130.38
Beilstein:
4342967
MDL number:
MFCD00008418
UNSPSC Code:
12352302
PubChem Substance ID:
24854927
NACRES:
NA.22

form

liquid

Quality Level

200

concentration

2.0 M in DMF

density

1.103 g/mL at 25 °C

SMILES string

CO[Mg]OC(=O)OC

InChI

1S/C2H4O3.CH3O.Mg/c1-5-2(3)4;1-2;/h1H3,(H,3,4);1H3;/q;-1;+2/p-1

InChI key

PNVKCUSCADAAMP-UHFFFAOYSA-M

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General description

Magnesium methyl carbonate is also known as Stile′s reagent. It is used as a carboxylating agent for the α-carboxylation of nitroalkanes, ketones, lactones, hydantoins, and phenols.

Signal Word

Danger-Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

136.4 °F - closed cup

Flash Point(C)

58 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH SVHC Candidate List

CAS No.

EU REACH Annex XVII (Restriction List)

CAS No.

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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De-Sheng Song et al.
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To evaluate the efficacy and safety of trabeculectomy (Trab) with mitomycin-C (MMC) versus Trab with implant. Studies published in different languages were retrieved by systematically searching Embase, PubMed, Cochrane library, China Biology Medicine disc, and Google Scholar from 1966 to
Aleksandra Wlaź et al.
Acta ophthalmologica, 97(6), e817-e826 (2019-03-30)
To compare the efficacy and safety of collagen matrix implant (Ologen® ; OLO) with mitomycin C (MMC) in phacotrabeculectomy. Prospective, single-centre, nonblinded, randomized controlled trial. A total of 53 eyes of 45 patients were enrolled in the study protocol with
Mara Colombo et al.
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Although the spliceogenic nature of the BRCA2 c.68-7T > A variant has been demonstrated, its association with cancer risk remains controversial. In this study, we accurately quantified by real-time PCR and digital PCR (dPCR), the BRCA2 isoforms retaining or missing exon 3.
Akbar Adjie Pratama et al.
Scientific reports, 7(1), 9156-9156 (2017-08-24)
Bacteriophages constitute key gene transfer agents in many bacteria. Specifically, they may confer gene mobility to Paraburkholderia spp. that dwells in soil and the mycosphere. In this study, we first screened mycosphere and bulk soils for phages able to produce
Tao Chen et al.
IEEE transactions on pattern analysis and machine intelligence, 40(10), 2522-2528 (2017-09-30)
The marriage between the deep convolutional neural network (CNN) and region proposals has made breakthroughs for object detection in recent years. While the discriminative object features are learned via a deep CNN for classification, the large intra-class variation and deformation
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