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206245

Sigma-Aldrich

Iridium(III) chloride hydrate

reagent grade

Synonym(s):

IrCl3, Iridium trichloride hydrate

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About This Item

Linear Formula:
IrCl3 · xH2O
CAS Number:
14996-61-3
Molecular Weight:
298.58 (anhydrous basis)
EC Number:
233-044-6
MDL number:
MFCD00149749
UNSPSC Code:
12352300
PubChem Substance ID:
24852388
NACRES:
NA.22

grade

reagent grade

Quality Level

100

form

solid

reaction suitability

core: iridium
reagent type: catalyst

density

5.3 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

[H]O[H].Cl[Ir](Cl)Cl

InChI

1S/3ClH.Ir.H2O/h3*1H;;1H2/q;;;+3;/p-3

InChI key

MJRFDVWKTFJAPF-UHFFFAOYSA-K

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General description

Iridium(III) chloride hydrate is an inorganic compound used as a catalyst as well as a reagent in organic synthesis. It is used as the source of iridium in the preparation of iridium nanocatalysts.

Application

Iridium(III) chloride hydrate can be used as a precursor in the preparation of:
  • Iridium-incorporated cobalt nanofibers.
  • Carbon-supported iridium catalyst for the hydrodeoxygenation of hydroxymethylfurfural.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319

Hazard Classifications

Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Maximilian Moser et al.
Angewandte Chemie (International ed. in English), 53(33), 8628-8633 (2014-06-04)
Rutile TiO2 is a heavily investigated oxide with, to date, scarce applications in industrial catalysis. The inactivity of this material in oxidations has been related to its inability to dissociate molecular oxygen. Herein we show how rutile catalyzes the oxidation

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