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P5833

Sigma-Aldrich

Kaliumcarbonat

BioXtra, ≥99.0%

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About This Item

Lineare Formel:
K2CO3
CAS-Nummer:
Molekulargewicht:
138.21
Beilstein:
4267587
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:
NACRES:
NA.21

Produktlinie

BioXtra

Qualitätsniveau

Assay

≥99.0%

Form

powder

Verunreinigungen

≤0.0005% Phosphorus (P)
≤0.1% Insoluble matter

pH-Wert

11-13 (25 °C, 138 g/L)

mp (Schmelzpunkt)

891 °C (lit.)

Löslichkeit

H2O: 1 M, clear, colorless

Anionenspuren

chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.02%

Kationenspuren

Al: ≤0.0005%
Ca: ≤0.001%
Cu: ≤0.0005%
Fe: ≤0.0005%
Mg: ≤0.0005%
NH4+: ≤0.05%
Na: ≤0.5%
Pb: ≤0.001%
Zn: ≤0.0005%

SMILES String

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChIKey

BWHMMNNQKKPAPP-UHFFFAOYSA-L

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Allgemeine Beschreibung

Potassium carbonate is an inorganic base that is used in the alkylation of phenols and 1,3-dicarbonyl compounds, as well as the generation of sulfur and phosphorus ylides. It is also used to dry organic solvents.

Anwendung

Potassium carbonate can be used as a catalyst in the:
  • Markovnikov addition reactions.
  • Suzuki cross-coupling reactions.
It can also be used as a base for the N-arylation of benzamides via C-N coupling reaction.

Piktogramme

Exclamation mark

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

13 - Non Combustible Solids

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


Analysenzertifikate (COA)

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Potassium carbonate as a green catalyst for Markovnikov addition of azoles to vinyl acetate in PEG
Kidwai M, et al.
Green Chemistry Letters and Reviews, 6, 63-68 (2013)
Potassium Carbonate Promoted C-N Coupling Reaction between Benzamides and Aryl Iodides
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K Y Foo et al.
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This work explores the feasibility of orange peel, a citrus processing biomass as an alternative precursor for preparation of activated carbon (OPAC) via microwave assisted K(2)CO(3) activation. The operational parameters, chemical impregnation ratio, microwave power and irradiation time on the
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ortho-Arylation of ortho-substituted benzoic acids is a challenging process due to the tendency of the reaction products toward Pd-catalyzed protodecarboxylation. A simple method for preventing decarboxylation in sterically hindered benzoic acids is reported. The method described represents a reliable and
K Y Foo et al.
Bioresource technology, 102(20), 9794-9799 (2011-08-31)
Sunflower seed oil residue, a by-product of sunflower seed oil refining, was utilized as a feedstock for preparation of activated carbon (SSHAC) via microwave induced K(2)CO(3) chemical activation. SSHAC was characterized by Fourier transform infrared spectroscopy, nitrogen adsorption-desorption and elemental

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