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Azamethiphos

PESTANAL®, analytical standard

Synonym(e):

S-((6-Chloro-2-oxooxazolo[4,5-b]pyridin-3(2H)-yl)methyl) O,O-dimethyl phosphorothioate

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About This Item

Empirische Formel (Hill-System):
C9H10ClN2O5PS
CAS-Nummer:
35575-96-3
Molekulargewicht:
324.68
EG-Nummer:
252-626-0
MDL-Nummer:
MFCD00867611
UNSPSC-Code:
41116107
PubChem Substanz-ID:
329756653
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

100

Produktlinie

PESTANAL®

Haltbarkeit

limited shelf life, expiry date on the label

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Anwendung(en)

agriculture
environmental

Format

neat

Lagertemp.

2-8°C

SMILES String

COP(=O)(OC)SCN1C(=O)Oc2cc(Cl)cnc12

InChI

1S/C9H10ClN2O5PS/c1-15-18(14,16-2)19-5-12-8-7(17-9(12)13)3-6(10)4-11-8/h3-4H,5H2,1-2H3

InChIKey

VNKBTWQZTQIWDV-UHFFFAOYSA-N

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Allgemeine Beschreibung

Azamethiphos is classified under the heterocyclic organothiophosphate group of compounds.

Anwendung

Azamethiphos may be used as an analytical reference standard for the determination of azamethiphos in:
  • Salmon feed samples by ultra-high performance liquid chromatography combined with traveling-wave ion mobility/quadrupole time-of-flight mass spectrometry (UHPLC-TWIMS-QTOFMS).
  • Surface water samples by solid-phase extraction (SPE) and LC coupled to quadrupole-Orbitrap high resolution tandem mass spectrometry (Q-Orbitrap-MS).
  • Fish fillet samples by QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction and LC-QTOFMS.
  • Human serum samples by QuEChERS combined with LC coupled to tandem mass spectrometry (MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Empfohlene Produkte

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Rechtliche Hinweise

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1 - STOT SE 1

Zielorgane

Nervous system

Lagerklassenschlüssel

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

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Analysenzertifikate (COA)

Lot/Batch Number
BCCF3468
BCBV5727
BCBS0605V
SZBD338XV
SZBA337XV

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Die Dokumentenbibliothek aufrufen

Sükran Cakir et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 43(3), 443-450 (2005-02-01)
In this study, different concentrations of some organophosphate insecticides (methyl parathion, azamethiphos, dichlorvos and diazinon) have been evaluated for genotoxicity in the wing somatic mutation and recombination test (SMART) of Drosophila melanogaster. Third-instar larvae trans-heterozygous for two genetic markers mwh
Michael Kristensen et al.
Pest management science, 62(8), 738-745 (2006-05-24)
Anti-cholinesterase resistance is in many cases caused by modified acetylcholinesterase (MACE). A comparison was made of toxicological data and AChE activity gathered from 21 field populations and nine laboratory strains of houseflies, Musca domestica L., to elucidate the best way
M Kristensen et al.
Journal of economic entomology, 93(6), 1788-1795 (2001-01-06)
The organophosphorus insecticide, azamethiphos, is widely used throughout the world to control the housefly, Musca domestica (L.). Since its commercial introduction to Denmark in 1983 for this purpose, we have monitored the toxicity of azamethiphos to housefly populations at livestock
L Intorre et al.
Pharmacological research, 49(2), 171-176 (2003-12-04)
The safety of azamethiphos (AZA), an organophosphorous insecticide and the active ingredient of Salmosan, was evaluated in the European eel, seabass and rainbow trout. Fish were bathed in 0.1 ppm AZA for a period of 60, 120 or 240 min.
Margaret Brown et al.
Marine environmental research, 57(3), 155-169 (2003-10-29)
Acetylcholinesterase in mussel is potentially a useful biomarker of exposure to organophosphates (OP) in the marine environment. This study looked at cholinesterase activity in subcellular fractions of various tissues from the common mussel, Mytilus edulis. Measurement of enzyme rates demonstrated
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