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A32608

Sigma-Aldrich

Allylglycidylether

≥99%

Synonym(e):

1-Allyloxy-2,3-epoxypropan, Allyl-2,3-epoxypropylether

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About This Item

Empirische Formel (Hill-System):
C6H10O2
CAS-Nummer:
Molekulargewicht:
114.14
Beilstein:
105871
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12162002
PubChem Substanz-ID:
NACRES:
NA.23

Dampfdichte

3.9 (vs air)

Qualitätsniveau

Dampfdruck

4.7 mmHg ( 25 °C)

Assay

≥99%

Form

liquid

Brechungsindex

n20/D 1.433 (lit.)

bp

154 °C (lit.)

Dichte

0.962 g/mL at 25 °C (lit.)

SMILES String

C=CCOCC1OC1

InChI

1S/C6H10O2/c1-2-3-7-4-6-5-8-6/h2,6H,1,3-5H2

InChIKey

LSWYGACWGAICNM-UHFFFAOYSA-N

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Allgemeine Beschreibung

Allyl glycidyl ether (AGE) is a monomer that acts as a building block in the polymerization of poly(allyl glycidyl ether) by anionic ring opening mechanism. It is industrially prepared by the reacting allyl alcohol and epichlorohydrin.

Anwendung

Useful in hydrosilylation, including the H2PtCl6·xH2O (cat. no. 206083) catalyzed hydrosilylation of siloxanes to epoxysiloxanes.
AGE can be used as a terminal epoxy group in the development of adhesive surfaces by hydrosilylation process. It can also be used in the synthesis of polymeric electrolytes for the fabrication of lithium batteries.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Zielorgane

Respiratory system

WGK

WGK 3

Flammpunkt (°F)

134.6 °F

Flammpunkt (°C)

57 °C

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Fatima M Plieva et al.
Journal of separation science, 27(10-11), 828-836 (2004-09-10)
Supermacroporous monolithic polyacrylamide (pAAm)-based columns have been prepared by radical cryo-copolymerization (copolymerization in the moderately frozen system) of acrylamide with functional co-monomer, allyl glycidyl ether (AGE), and cross-linker N,N'-methylene-bis-acrylamide (MBAAm) directly in glass columns (ID 10 mm). The monolithic columns
Macromolecules, 27, 3397-3397 (1994)
Qin Zeng et al.
International journal of nanomedicine, 7, 985-997 (2012-03-14)
The generation of anti-adenovirus neutralizing antibody (NAb) in humans severely restricts the utilization of recombinant adenovirus serotype 5 (Ad5) vectors in gene therapy for a wide range of clinical trials. To overcome this limitation, we ionically complexed Ad5 with a
Cancan Li et al.
Langmuir : the ACS journal of surfaces and colloids, 27(17), 11174-11179 (2011-08-02)
Poly(allyl glycidyl ether) (PAGE) and poly(ethylene glycol) (PEG) blocks were sequentially grown via anionic polymerization to form four block copolymer arms on a cholic acid (CA) core, yielding star block copolymers (CA(AGE(8)-b-EG(n))(4)) with low polydispersities (ca. 1.05). The introduction of
M Chiari et al.
Electrophoresis, 21(8), 1521-1526 (2000-06-01)
A fully automated coating procedure was devised based on adsorption of a new polymer, poly(dimethylacrylamide-co-allyl glycidyl ether) onto the capillary surface. The whole procedure takes less than 30 min and does not require the use of organic solvents, viscous solutions

Artikel

Discussion of synthetic modifications to gelatin, improving the three-dimensional (3D) print resolution, and resulting material properties.

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