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Sigma-Aldrich

Lithiumaluminiumhydrid

greener alternative

hydrogen-storage grade

Synonym(e):

LAH, Lithiumalanat, Lithiumtetrahydridoaluminat, Lithiumtetrahydroaluminat

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About This Item

Lineare Formel:
LiAlH4
CAS-Nummer:
16853-85-3
Molekulargewicht:
37.95
EG-Nummer:
240-877-9
MDL-Nummer:
MFCD00011075
UNSPSC-Code:
26111700
PubChem Substanz-ID:
329761015
NACRES:
NA.23

Qualität

hydrogen-storage grade

Qualitätsniveau

100

Assay

>99.95%

Form

pellets

Eignung der Reaktion

reagent type: reductant

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp (Schmelzpunkt)

125 °C (dec.) (lit.)

Grünere Alternativprodukt-Kategorie

, Enabling

SMILES String

[Li].[AlH3]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChIKey

OCZDCIYGECBNKL-UHFFFAOYSA-N

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Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Anwendung

Lithium aluminum hydride (LAH) is majorly used in hydrogen storage applications. Its properties include high gravimetric and volumetric hydrogen densities. It can also be used as a reducing agent in the preparation of reduced graphene oxide (rGO).

Hinweis zur Analyse

Hydrogen content, XRD plots and metal purity data are available upon request.

Piktogramme

FlameCorrosion
GHS02,GHS05

Signalwort

Danger

H-Sätze

H260,H314

Gefahreneinstufungen

Eye Dam. 1 - Skin Corr. 1A - Water-react 1

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Die Dokumentenbibliothek aufrufen

A first-principles study of the electronic structure and stability of a lithium aluminum hydride for hydrogen storage
Song Y, et al.
The Journal of Physical Chemistry B, 110(13), 6906-6910 (2006)
Reversible hydrogen storage via titanium-catalyzed LiAlH4 and Li3AlH6
Chen J, et al.
The Journal of Physical Chemistry B, 105(45), 11214-11220 (2001)
Diastereoselective reductive amination of aryl trifluoromethyl ketones and alpha-amino esters.
Greg Hughes et al.
Angewandte Chemie (International ed. in English), 46(11), 1839-1842 (2007-04-24)
Krishnananda Samanta et al.
Bioorganic & medicinal chemistry letters, 20(1), 283-287 (2009-11-26)
A series of new benzoxazepine derivatives substituted with different alkoxy and aryloxy group were synthesized comprising synthetic steps of Mitsunobu reaction, lithium aluminum hydride (LAH) reduction, followed by debenzylation and finally intramolecular Mitsunobu cyclization. The new benzoxazepines specifically inhibited growth
Damián E Bikiel et al.
Inorganic chemistry, 44(15), 5286-5292 (2005-07-19)
The nature of the solute species present in ethereal solutions of LiAlH(4) is of crucial importance for understanding the mechanisms for the reduction of ketones and other functional groups by LiAlH(4). We have employed a combination of theoretical and experimental
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