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Sigma-Aldrich

5-Iodindol

97%

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About This Item

Empirische Formel (Hill-System):
C8H6IN
CAS-Nummer:
16066-91-4
Molekulargewicht:
243.04
MDL-Nummer:
MFCD00220065
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24880134
NACRES:
NA.22

Qualitätsniveau

100

Assay

97%

mp (Schmelzpunkt)

101-104 °C (lit.)

SMILES String

Ic1ccc2[nH]ccc2c1

InChI

1S/C8H6IN/c9-7-1-2-8-6(5-7)3-4-10-8/h1-5,10H

InChIKey

TVQLYTUWUQMGMP-UHFFFAOYSA-N

Verwandte Kategorien

Allgemeine Beschreibung

5-Iodoindole can be synthesized via nitration of m-toluidine.

Anwendung

5-Iodoindole (5-iodogramine) may be used in the synthesis of the following:
  • 3-dimethylaminomethyl-5-iodoindole via reaction with dimethyl amine and formaldehyde
  • 5-ethynyl-1H-indole obtained via refluxing with trimethylsilylacetylene in the presence of triethylamine, catalyzed by palladium and copper(I)iodide in acetonitrile
  • 5-(3-hydroxyprop-1-enyl)-1H-indole via reaction with allyl alcohol in the presence of triphenyl phosphine, palladium acetate and silver acetate in dimethylformamide
  • 5-(3-benzyloxyprop-1-enyl)-1H-indole via reaction with allylbenzyl ether in the presence of triphenyl phosphine, palladium acetate and silver acetate in dimethylformamide
  • 5-(2-phenylethynyl)-1H-indole via refluxing with phenylacetylene catalyzed by copper(I)iodide and palladium in the presence of triethylamine in acetonitrile

Piktogramme

Exclamation mark
GHS07

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

Analysenzertifikate (COA)

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