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Merck

440272

Sigma-Aldrich

Dichlordimethylsilan

≥99.5%

Synonym(e):

DMDCS, Dimethyl-dichlorsilan

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About This Item

Lineare Formel:
(CH3)2SiCl2
CAS-Nummer:
Molekulargewicht:
129.06
Beilstein:
605287
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.22

Qualitätsniveau

Assay

≥99.5%

Form

liquid

Brechungsindex

n20/D 1.404 (lit.)

bp

70 °C (lit.)

mp (Schmelzpunkt)

−76 °C (lit.)

Dichte

1.07 g/mL at 25 °C (lit.)

Lagertemp.

2-8°C

SMILES String

C[Si](C)(Cl)Cl

InChI

1S/C2H6Cl2Si/c1-5(2,3)4/h1-2H3

InChIKey

LIKFHECYJZWXFJ-UHFFFAOYSA-N

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Anwendung

Common reagent for synthesis of optically active ansa-mettallocene polymerization catalysts.
Used to prepare a resin bound siloxane with reactivity towards tertiary alcohols.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

33.8 °F - closed cup

Flammpunkt (°C)

1 °C - closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Sigma-Aldrich

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Sigma-Aldrich

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Journal of the American Chemical Society, 126(26), 8216-8231 (2004-07-01)
A series of enantiopure C1-symmetric metallocenes, [(SiMe2)2[eta5-C5H(CHMe2)2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-2, [(SiMe2)2[eta5-C5H(CHEt2)2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-6, and [(SiMe2)2[eta5-C5HCy2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-7 (Cy = cyclohexyl), zirconocene dichlorides that have an enantiopure methylneopentyl substituent on the "upper" cyclopentadienyl ligand, and diastereomerically pure precatalysts, [(SiMe2)2[eta5-C5H((S)-CHMeCy)(CHMe2)][eta5-C5H3]]ZrCl2, (S)-8a and (S)-8b, which have an
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